CHAPTER 5 METALS AND NON-METALS

Textual question: (Page no.92)

Q.1. Name five metals and non-metals.

Ans:- 

 Five metals : sodium, potassium, aluminium, magnesium and copper. 

Five non-metals: sulphur, chlorine, bromine, hydrogen and carbon.

Q.2. Name one metal and one non-metal which exist in liquid state at room temperature.

Ans:- One metal that exist in liquid state at room temperature is mercury and the non-metal that exist as liquid is bromine.

Q.3. Give an example of metal which

i)Can be easily cut with a knife?

ii)Is the best conductor of heat?

iii)Is a poor conductor of heat?

 Ans:-

i) Sodium

ii) Silver

iii) Mercury

Q.4. What is meant by saying that metals are malleable and ductile?

Ans:- Metals are malleable means they can be beaten into sheets and ductile means they can be drawn into wires.

Q.5. Which property of copper and aluminium make them suitable for making electric wires?

Ans:- The property of copper and aluminium being good conductors of electricity makes them suitable for making electric wire.

Q.6. Name a non-metal which conduct electricity. 

Ans:- Carbon in the form of graphite.

Q.7. Write the equations for the reactions.

a)potassium with water

b)red hot iron with steam

c)zinc with dilute sulphuric acid 

Ans:-

a)Potassium with water -

2K + 2H2O →2KOH + H2

b)Red hot iron with steam -

3Fe + 4H2O → FeOFe2O3 + 4H2

 c)Zinc with dilute sulphuric acid -

Zn + H2SO4 → ZnSO4 + H2

Q.8. How do metals differ from non-metals in their reaction with oxygen and product is dissolved in water.

Ans:- Metals react with oxygen to form basic oxide and basic oxide dissolves in water to form alkalis.

Eg.

4Na + O2 → 2Na2O 

Na2O + HO2 → 2NaOH

Non-metals react with oxygen to give acidic oxides which ion dissolving in water form acids.

E.g.

S(s) + O2 (g) → 2SO2(g)

SO2(g) + H2O(l) → H2SO3(l)


Textual Questions(Page No - 105)

Q1. Name two metals which are found in nature in the free-state.

Ans:- Gold and silver

Q2. Define the following terms – 

i) Mineral ii) Ores iii) Gangue 

Ans:-

i)Mineral- The natural material in which the metals or their compounds are found in earth’s crust is called minerals.

ii)Ores- Ores are those minerals from which metals can be extracted profitably.

iii)Gangue- The unwanted impurities such as earthy, sandy and rocky materials associated with the ores are called gangue or matrix.


Q.3. Differentiate between roasting and calcinations. 

Ans:-

DIFFERENCE

ROASTING

CALCINATION

1. It is the process of strong heating an ore

in the presence of air

1. It is the process of heating an ore

strongly in limited supply of air.

2.  In    this    process,    a    sulphide    ore    is converted into oxide.

2. In this process, a carbonate ore is converted into oxide.


Q.4. Name two sulphide and two oxide ore. Ans:-

Two sulphide ores – Iron pyrite (FeS), copper pyrite(𝐶𝑢𝐹𝑒𝑆2) 

Two oxide ores – Bauxite (𝐴𝑙2𝑂32𝐻2𝑂), Haematite (𝐹𝑒2𝑂3)

Q.5. Name the systematic steps involved in metallurgy.

 Ans:-

(i)Concentration or enrichment of ores

(ii)Extraction of metal from the concentrated ores

(iii)Refining or purification of the impure metal

Q.6. Write the chemical process used for obtaining a metal from its oxide.

Ans:- The chemical process is reduction. In this process the oxides of metals are mixed with coke, carbon monoxide or other element which has high affinity for oxygen.



Q.7. Give an example of a sulphide ore which is reduced to metal by heating alone. Give the relevant equation involved.

Ans:- Cinnabar (HgS) is the sulphide ore.

The relevant equation is




Q.8. Why aluminium cannot be obtained by reduction of its oxide with coke?

Ans:-Aluminium cannot be obtained by reduction of its oxide with coke because the affinity of oxygen for the metal is greater than its affinity for carbon.


Q.9. Explain how the following metals can be obtained from their compounds by reduction process

(a)Metal X which is low in activity series.

(b)Metal Y which is moderately reactive.

(c)Metal Z which is high in the reactivity series.

 Ans:-

(a)Metal X is low in reactivity the sulphur and oxides of these metals can be reduced to metals by heating alone.

(b)Metal Y is moderately reactive

The sulphide or carbonate ore of these metals is converted into corresponding metal oxides before reduction.

The oxides of this metal react with suitable quantity of coke on carbon monoxide on other elements having affinity for oxygen to form metal.

E.g. ZnO(s) + C(s) →Zn(s) + CO(g)

(c)Metal Z is highly reactive and has great affinity for oxygen. So the metal is obtained by electrolytic method.

Sodium can be manufactured by electrolysis of fused sodium chloride.

E.g.

               fusion          

NaCl(s) –––--→ Na+(l)+ Cl−(l)

At cathode

Na+ + e−   →  Na[reduced] 

At anode

2Cl−  →  Cl2 + 2e−[oxidation]

 Q.10. An alloy solder is used in electronic industry to join different electronic components. What are the constituents of their alloy?

Ans:- The constituents of solder is lead(40-60)% and tin(40 -60%).

Q.11. Which alloy is used for making bodies of aircrafts? What is the approximate composition?

Ans:- Duralumin is used for making aircrafts. The approximate composition is Aluminium - 95%

Copper – 4%

Manganese – 0.5%

Magnesium – 0.5%

Textual Question (Page 107)

Q.1. Give five points to distinguish metals from non-metals. 

Ans:- Five points to distinguish metals from non-metals

DIFFERENCES

METALS

NON-METALS

1. Metals are malleable and ductile

1. Non-metals    are    not    malleable    and

ductile

2. Metals are good conductors of heat and

electricity

2. They are poor conductors of heat and

conductor electricity except graphite.

3. Metals are lustrous or shiny

3. Non-metals are not lustrous

4. Generally metals are strong and have high

tensile strength

4. Generally they are weak and have low

tensile strength

5. They have high melting and boiling point

except mercury.

5. They have low melting and boiling point

except carbon and silicon


Q.2. You are given a hammer, a battery, a bulb wires and a switch

(a) How would you use them to distinguish between samples and metals and non-metals.

(b) Assess the usefulness of these tests. 

Ans:-

If the sample can be beaten into sheets by hammering, then the sample is a metal and if it is broken into pieces then it is non-metal.

An arrangement is set up as shown in the figure.




If the bulb starts glowing then the sample is metal, as metal is a good conductor  of  electricity.

If the bulb does not glow, then the sample is non – metal. Usefulness of these tests:

These tests can be used for identifying metals with the exception of some  metals  like  sodium, potassium.

Metals can be beaten into sheets and can be used to cover food items.

E.g. Aluminium foil.


Q.3. Frying pans and boilers are generally made of aluminium but not from steel.why? Give reasons.

Ans:- Frying pans and boilers are generally made of aluminium but not from steel because  the thermal conductivity of aluminium is higher than steel and moreover it is resistant to corrosion.


Q.4. Distinguish between metals and non-metals on the basis of their chemical properties. Give three points.

Ans:-

DIFFERENCES

METALS

NON-METALS

1. Oxides of metals are basic in

nature

1. Oxides of non-metals are acidic or neutral in

nature.

2. Metals react with dilute acids to

release hydrogen.

2. Non-metals do not react with dilute acids.

3. Metals displace hydrogen from

water.

3. Non-metals do not react with water.


Q.5. What are amphoteric oxides? Give two examples of amphoteric oxides.
Ans:-Those metal oxides which show basic as well as acidic behaviour are known as amphoteric oxides.
Eg. Aluminium Oxide and Zinc Oxide.

Q.6. Name two metals which will displace hydrogen from dilute acids and two metals which will not displace.
Ans:- Two metals which will displace hydrogen from dilute acids are mercury and zinc. Two metals that will not displace hydrogen from dilute acids are– copper and silver.

Q.7. Differentiate between
i) mineral and ore
ii) Alloy and amalgam 
Ans:-
(i) All minerals are not ores (e.g. Clay) while all ores are minerals (e.g. Bauxite and  Cryolite).
(ii) An alloy is a mixture of a metal with one or more metals or non-metals whereas an amalgam is an alloy containing mercury as one of the constituents.

Q.8. What are common methods of ore concentration? 
Ans:-The common methods of ore concentration are –
a) Gravity separation or hydraulic washing
b) Froth floatation process
c) Electromagnetic separation
d) Leaching

Q.9. Name the process that is used to concentrate sulphide ore. Describe the stages that are involved in the conversion of concentrated sulphide ore into corresponding metal.
Ans: Froth floatation process is used to concentrate sulphide ore.
The concentrated sulphide ore is roasted in the presence of oxygen and converted into oxides. Eg. 2𝑍𝑛𝑆(𝑠) + 3𝑂2 ––→ 2𝑍𝑛𝑂(𝑠) + 2𝑆𝑂2

The oxide is again reduced to metal by heating with coke.

𝑍𝑛𝑂(𝑠) + 𝐶(𝑠) ––→ 𝑍𝑛(𝑠) + 𝐶𝑂(𝑔)

The carbon monoxide so formed also act as reducing agent

𝑍𝑛𝑂(𝑠) + 𝐶𝑂(𝑔) ––→ 𝑍𝑛(𝑠) + 𝐶𝑂2

Q.10. How is impure metal refined electrolytically?
Ans:- The impure metal is refined by the process of electrolytic refining in which –

(i) A thick block of impure metal is used as anode.
(ii) A thin strip of pure metal is used as cathode.
(iii) A water soluble salt of the metal to be refined is taken as electrolyte.

When electric current pass through the electrolyte, the pure metal from the anode pass into the solution in the form of metal ions. An equal amount of metal ions from the solution are deposited on cathode as pure metal.
The soluble impurities go into the solution but the insoluble impurities settle down below the anode as anode mud.

Q.11. What is an alloy? Write the composition and two uses of brass and bronze.

Ans: An alloy is a homogeneous mixture of one metal with one or more metal or non-metal which is fused in molten state.
The composition of brass is – 60 to 80% of copper and 0 to 40% of zinc. Brass is used in making utensil, hardware and radiator cores etc.
Whereas, the bronze contains 75 to 90% of copper and 10 to 25% of tin. Bronze is used in making statues, coins, cooking utensils etc.
 



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